Two new thiophen derivatives, metabolites of Daedalea juniperina Murr, have been identified as 2-lactoyl-5-(prop-1-ynyl)thiophen (IX) and 2-(prop-1-ynyl)-5-pyruvoylthiophen (XI). Syntheses of the diketone (XI) and related thiophen derivatives are described.
R. F. Curtis and J. A. Taylor, J. Chem. Soc. C, 1969, 1813 DOI: 10.1039/J39690001813
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