Azobenzene and substituted azobenzenes react with carbonyls of iron to give mono-, di-, and tri-iron carbonyl derivatives. The first contain the metal σ-bonded to one of the aromatic rings; the di- and probably also the tri-iron complexes contain the rearranged skeleton of o-semidine. Bisazoarene complexes are formed from the azoarenepalladium chlorides by reaction with disodium tetracarbonylferrate.
M. M. Bagga, W. T. Flannigan, G. R. Knox and P. L. Pauson, J. Chem. Soc. C, 1969, 1534 DOI: 10.1039/J39690001534
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