Lithium isopropoxide is an efficient hydride-donor for the reduction of many ketones. Sodium and potassium isopropoxides are less effective. Cyclohexanones, including steroid ketones, give different axial : equatorial ratios of alcohols, depending upon the isopropoxide used.
D. N. Kirk and A. Mudd, J. Chem. Soc. C, 1969, 804 DOI: 10.1039/J39690000804
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