Alkyl substituted cyclohex-2-ene-1,4-diones have been prepared by the pyrolysis of the appropriate 2,3,4a,5,8,8a-hexahydro-5,8-methanonaphthoquinones. The stereochemistry of some of these intermediates is discussed and the extension of the synthesis to monoacetals of cyclohex-2-ene-1,4-diones is described.
D. D. Chapman, W. J. Musliner and J. W. Gates, J. Chem. Soc. C, 1969, 124 DOI: 10.1039/J39690000124
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