Issue 0, 1969
From the journal:

Journal of the Chemical Society B: Physical Organic

Homogeneous benzylic oxidation catalysed by some complexes of the platinum group

Jochanan Blum,   James Y. Becker,   Hedva Rosenman  and  Ernst D. Bergmann  

Abstract

The autoxidation of ethylbenzene and related compounds in the presence of a number of organic compounds of Rh, Ru, Pt, Ir, and Pd is investigated: RhCl(PPh3)3 is found to be a most effective catalyst in this reaction, whilst the application of RuCl2(PPh3)3 is limited to the oxidation of non-halogenated alkylarenes and requires the addition of polyhalogenoalkane as co-catalyst. The reaction mechanism is discussed.

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Article information

DOI
https://doi.org/10.1039/J29690001000
Article type
Paper

J. Chem. Soc. B, 1969, 1000-1004

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Homogeneous benzylic oxidation catalysed by some complexes of the platinum group

J. Blum, J. Y. Becker, H. Rosenman and E. D. Bergmann, J. Chem. Soc. B, 1969, 1000 DOI: 10.1039/J29690001000

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