The organoboranes derived from enamines are converted into olefins in hign yield by ‘protonolysis’ with propionic acid in diglyme. The hydroboration reaction gives only β-amino-organoboranes except with the enamines of disubstituted acetaldehydes when a considerable proportion of the α-amino-borane is formed.
J. W. Lewis and A. A. Pearce, J. Chem. Soc. B, 1969, 863 DOI: 10.1039/J29690000863
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