Rates of acidic hydrolysis of dialkyl methylphosphonates [(RO)2P(O)Me and (RO)(EtO)P(O)Me, where R is primary, secondary (mainly), and tertiary] at 100° in 50% aqueous dioxan, containing benzenesulphonic acid (1 N), have been measured and the relative rates of hydrolysis are compared with the previously reported relative rates of ageing of phosphonylated cholinesterases.
J. I. G. Cadogan, D. Eastlick, F. Hampson and R. K. Mackie, J. Chem. Soc. B, 1969, 144 DOI: 10.1039/J29690000144
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