SCHEDULED MAINTENANCE:
N-Phenyl substitution of amino- and imino-groups in benzamidines is shown to reduce basic strength by factors of ca. 10 and 1000, respectively. The configuration of the imino-N-phenyl ring is discussed. The structure of the predominant tautomer of N-(3-diethylaminopropyl)-N′-phenylbenzamidine is indicated.
J. A. Smith and H. Taylor, J. Chem. Soc. B, 1969, 66 DOI: 10.1039/J29690000066
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