SCHEDULED MAINTENANCE:
The partial rate factor for the meta-nitration of benzylidyne trifluoride by nitric acid in sulphuric acid is 6·7 × 10–5. Evidence is presented to support a mechanism for the hydrolysis of benzylidyne trifluoride to form benzoic acid in concentrated sulphuric acid which involves a transition state similar in structure to the carbonium ion PhCF2+.
R. G. Coombes, R. B. Moodie and K. Schofield, J. Chem. Soc. B, 1969, 52 DOI: 10.1039/J29690000052
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