Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Silicon–phosphorus hydrides. Part III. Exchange reactions of monosilylphosphine with chlorinated germanes and silanes

J. E. Drake,   N. Goddard  and  C. Riddle  

Abstract

Monosilylphosphine reacts with dichlorogermane, chloro(methyl)germane, dichloro(methyl)germane, monochloro[2H3]silane, dichlorosilane, monochlorodisilane, 1,2-dichlorodisilane, and 1,1,2-trichlorodisilane to form GeH2Cl·PH2, MeGeH2·PH2, MeGeHCl·PH2, SiD3·PH2, SiH2Cl·PH2, SiH3·SiH2·PH2, SiH2Cl·SiH2·PH2, PH2·SiH2·SiH2·PH2, and SiHCl2·SiH2·PH2. The formation of the mixed hydrides, which in some cases is only transient, is confirmed by their 1H n.m.r. spectra.

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Article information

DOI
https://doi.org/10.1039/J19690002704
Article type
Paper

J. Chem. Soc. A, 1969, 2704-2709

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Silicon–phosphorus hydrides. Part III. Exchange reactions of monosilylphosphine with chlorinated germanes and silanes

J. E. Drake, N. Goddard and C. Riddle, J. Chem. Soc. A, 1969, 2704 DOI: 10.1039/J19690002704

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