Silicon–phosphorus hydrides. Part III. Exchange reactions of monosilylphosphine with chlorinated germanes and silanes
Abstract
Monosilylphosphine reacts with dichlorogermane, chloro(methyl)germane, dichloro(methyl)germane, monochloro[2H3]silane, dichlorosilane, monochlorodisilane, 1,2-dichlorodisilane, and 1,1,2-trichlorodisilane to form GeH2Cl·PH2, MeGeH2·PH2, MeGeHCl·PH2, SiD3·PH2, SiH2Cl·PH2, SiH3·SiH2·PH2, SiH2Cl·SiH2·PH2, PH2·SiH2·SiH2·PH2, and SiHCl2·SiH2·PH2. The formation of the mixed hydrides, which in some cases is only transient, is confirmed by their 1H n.m.r. spectra.