Acetato- and trifluoroacetato-triphenylphosphine gold(I) have been prepared by reaction of the silver salts with chloro(triphenylphosphine)gold(I). The acetate reacts with the acid HX to form the compounds Ph3PAuX and acetic acid. Reactions with alkyl halides yield alkyl acetates and halogeno(triphenylphosphine)gold(I). Reaction with bromine yields mono- and tri-bromo(triphenylphosphine)gold.
D. I. Nichols and A. S. Charleston, J. Chem. Soc. A, 1969, 2581 DOI: 10.1039/J19690002581
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