The isolation of divalent nickel complexes with the bidentate chelating agent 8-dimethylarsinoquinoline (8-dmaq) is reported. Both bis- and tris-chelates of the type Ni(8-dmaq)2X2(X = Cl–, Br–, I–, SCN–, and NO3) and Ni(8-dmaq)3X2(X = ClO4– and Ph4B–) are isolated, and their structures have been deduced from magnetic, conductivity, and spectral measurements.
G. A. Barclay, M. A. Collard, C. M. Harris and J. V. Kingston, J. Chem. Soc. A, 1969, 1684 DOI: 10.1039/J19690001684
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