Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Transition metal–carbon bonds. Part XIX. Some Dewar hexamethylbenzene derivatives of rhodium(I)

B. L. Shaw  and  G. Shaw  

Abstract

Treatment of [Rh2Cl2(C2H4)4] with hexamethylbicyclo[2,2,0]hexa-2,5-diene (DHMB) gives a bridged chlorocomplex [Rh2Cl2(C12H18)2] in which the DHMB is acting as a chelating diolefin. [Rh2Cl2(C12H18)2] has been converted into [Rh2Br2(C12H18)2], [RhY(C12H18)](Y = acac or C5H5), and [RhClZ(C12H18)](Z = PPh3, AsPh3, or isoquinoline). With allylmagnesium chloride [Rh2Cl2(C12H18)2] gives [Rh(C3H5)3]. I.r. and n.m.r. data are discussed.

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Article information

DOI
https://doi.org/10.1039/J19690001560
Article type
Paper

J. Chem. Soc. A, 1969, 1560-1562

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Transition metal–carbon bonds. Part XIX. Some Dewar hexamethylbenzene derivatives of rhodium(I)

B. L. Shaw and G. Shaw, J. Chem. Soc. A, 1969, 1560 DOI: 10.1039/J19690001560

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