Optically active co-ordination compounds. Part XV. Stereoselectivity in tris-(α-amino-acid) complexes of cobalt(III)
Abstract
The preparations and interconversions of the various isomers of [Co(L-α-amino-acidate)3] have been studied, by use of leucine, valine, and γ-methylglutamic acid. Absolute configurations are presented, with c.d. and o.r.d. data. The absolute configuration of β(+)[Rh(L-alaninate)3] is also given.
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