Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


A palladium–lead bonded complex

G. Carturan,   G. Deganello,   T. Boschi  and  U. Belluco  

Abstract

The preparation of a new metal–metal bonded PdII complex formulated as trans-[Pd(PEt3)2(PbPh3)2](I) is described. The reactions of (I) with hydrogen chloride, hydrogen, cyanide, and oxygen lead to cleavage of the intermetallic bond. A peculiar feature of this organolead–palladium(II) complex is its ability to promote the oxidation of isobutyl alcohol to aldehyde in the presence of molecular oxygen.

A comparative discussion of the stability of PdII and PtII metal–metal bonded complexes of type (I) is reported.

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Article information

DOI
https://doi.org/10.1039/J19690001142
Article type
Paper

J. Chem. Soc. A, 1969, 1142-1144

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A palladium–lead bonded complex

G. Carturan, G. Deganello, T. Boschi and U. Belluco, J. Chem. Soc. A, 1969, 1142 DOI: 10.1039/J19690001142

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