Isopropyl radicals are produced by photolysis of 2,2′-azopropane. In the presence of caesium vapour, high values for the disproportionation: combination ratio are observed. The intermediate formation of a caesium alkyl may account for this observation.
A. U. Chaudhry and B. G. Gowenlock, J. Chem. Soc. A, 1969, 560 DOI: 10.1039/J19690000560
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