Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Phosphite complexes of tin(II)

C. G. Davies,   J. D. Donaldson  and  W. B. Simpson  

Abstract

Evidence has been found for the presence of the species, SnHPO3, Sn(HPO3)22–, and Sn(HPO3)34– in solutions of tin(II) phosphite in the pH range 4·5–8. The solid complexes M4Sn(HPO3)3(M = NH4, Na, K, Rb, or Cs) have been prepared. The Mössbauer and i.r. spectra of the complexes are consistent with the presence of a pyramidal triphosphitostannate(II) ion in these materials. The thermal decomposition of the complexes is discussed and their X-ray data reported.

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Article information

DOI
https://doi.org/10.1039/J19690000417
Article type
Paper

J. Chem. Soc. A, 1969, 417-420

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Phosphite complexes of tin(II)

C. G. Davies, J. D. Donaldson and W. B. Simpson, J. Chem. Soc. A, 1969, 417 DOI: 10.1039/J19690000417

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