Issue 0, 1969

Some reactions of trisilylphosphine

Abstract

A study has been made of the reactions of trisilylphosphine with protonic acids, phosphorus trihalides, silyl iodide, methyl iodide, iodine, sulphur, carbon disulphide, carbon tetrachloride, pentacarbonyliron, and pentacarbonyl-methylmanganese. No derivatives of PV nor any mono- or di-silylphosphorus derivatives were detected in the products; trisilylphosphine is found to be an appreciably weaker nucleophile than trimethylphosphine.

Article information

Article type
Paper

J. Chem. Soc. A, 1969, 352-353

Some reactions of trisilylphosphine

E. A. V. Ebsworth, C. Glidewell and G. M. Sheldrick, J. Chem. Soc. A, 1969, 352 DOI: 10.1039/J19690000352

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