Issue 0, 1969
From the journal:

Journal of the Chemical Society A: Inorganic, Physical, Theoretical


Substituted trisilylamines. Part II. Reactions of amino- and hydroxysubstituted trisilylamines

R. P. Bush  and  N. C. Lloyd  

Abstract

The pyrolytic rearrangement of amino-substituted trisilylamines to the isomeric trisilazanes is probably an intramolecular transamination. The pyrolysis of (Me3Si)2N·Si(Me2)NH2(I) gives (Me3Si)2N·Si(Me2)·NH·SiMe3 when an acid catalyst is present; and similarly (Me3Si)2N·Si(Me2)·OH (II) gives (Me3Si)2N·Si(Me2)·O·SiMe3. The silanol (II) reacts with bis(methylamino)dimethylsilane to give [(Me3Si)2N·Si(Me2)·O·]2SiMe2 and with tetramethyldisilazane to give (Me3Si)2N·Si(Me2)·O·SiMe2H.

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Article information

DOI
https://doi.org/10.1039/J19690000257
Article type
Paper

J. Chem. Soc. A, 1969, 257-260

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Substituted trisilylamines. Part II. Reactions of amino- and hydroxysubstituted trisilylamines

R. P. Bush and N. C. Lloyd, J. Chem. Soc. A, 1969, 257 DOI: 10.1039/J19690000257

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