The ν(CO) spectra of Mo(CO)4 bipy (bipy = 2,2′-bipyridyl), cis-[W(CO)2{o-C6H4(PEt2)2}2],Cr(CO)3(π-mesitylene), and Cr(CO)3(π-C6H5·CO2Me) are examined in solution in n-hexane–chloroform or –nitrobenzene mixtures; the ν(NO) spectrum of Fe(NO)(S2CNMe2)2 is studied in benzene–nitromethane mixtures. Structure observed on the ν(CO) bands is discussed in terms of formation of solvent–solute complexes.
D. M. Adams, J. Chem. Soc. A, 1969, 87 DOI: 10.1039/J19690000087
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