The N-chloro-derivative of indano [1,2-b]aziridine undergoes spontaneous dehydrochlorination to give isoquinoline, in an aza-analogue of the cyclopropyl to allyl cation rearrangement.
D. C. Horwell and C. W. Rees, J. Chem. Soc. D, 1969, 1428a DOI: 10.1039/C2969001428A
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