The kinetics, activation parameters, solvent effects, and catalytic activities in the isomerization of cis-[Pt(Bun3P)2Cl2] indicate that the mechanism does not involve cosecutive displacements; pseudorotation of a pentaco-ordinate intermediate should be considered.
P. Haake and R. M. Pfeiffer, J. Chem. Soc. D, 1969, 1330a DOI: 10.1039/C2969001330A
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