The pressure-dependence of triplet yield in the gas phase has been confirmed for several aromatic molecules and a mechanism is suggested in which vibrational relaxation becomes the rate-determining process at low pressures.
C. W. Ashpole, S. J. Formosinho and G. Porter, J. Chem. Soc. D, 1969, 1305b DOI: 10.1039/C2969001305B
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