The effect of remote alkyl substituents on the chemical shifts of methine protons in cyclohexyl compounds probably arises from changes in the polarisability of the ring due to deformation (and hence the inductive effect of the C-1 substituent), and not only from the accompanying changes in anisotropic shielding.
G. E. Hawkes and J. H. P. Utley, J. Chem. Soc. D, 1969, 1033b DOI: 10.1039/C2969001033B
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...