In the two isomers of C5H5RhC5Me5H, the exo-substituent is more reactive than the endo-substituent. The endo-H is postulated to react via an intramolecular transfer to the other ring.
K. Moseley and P. M. Maitlis, J. Chem. Soc. D, 1969, 616b DOI: 10.1039/C2969000616B
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