Methyl 3-phenylbut-2-en-oate is homogeneously hydrogenated at a rhodium complex formed in (+)- or (–)-1-phenylethylformamide to give (+)- or (–)-methyl 3-phenylbutanoate in better than 50% optical yield.
P. Abley and F. J. McQuillin, J. Chem. Soc. D, 1969, 477b DOI: 10.1039/C2969000477B
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