Two thiourea derivatives, 3-(diphenylphosphinothioyl)-1-phenylthiourea and 3-(diphenylphosphinothioyl)-1,1-diethylthiourea, behave as bidentate ligands towards NiII and PdII to produce new square-planar complexes, while the latter ligand gives a tetrahedral complex with CoII.
I. Ojima, T. Iwamoto, T. Onishi, N. Inamoto and K. Tamaru, J. Chem. Soc. D, 1969, 1501 DOI: 10.1039/C29690001501
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