Issue 24, 1969

Intramolecular rearrangements with nuclear magnetic resonance emission. Nuclear polarization in 1,2-shifts of quaternary nitrogen intermediates

Abstract

1 H n.m.r. emission at both α- and β-positions in Stevens rearrangement products, but not eliminated olefins, from quaternary ammonium intermediates is indicative of caged radical pairs in the migration process.

Article information

Article type
Paper

J. Chem. Soc. D, 1969, 1460-1462

Intramolecular rearrangements with nuclear magnetic resonance emission. Nuclear polarization in 1,2-shifts of quaternary nitrogen intermediates

A. R. Lepley, J. Chem. Soc. D, 1969, 1460 DOI: 10.1039/C29690001460

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