Issue 23, 1969

Geometrical orbital overlap requirements in allowed thermal reactions: the trans,trans Cope rearrangement of 3,7-dideuteriobicyclo[3,3,0]octa-2,6-diene

Abstract

The degenerate trans,trans Cope rearrangement of bicyclo[3,3,0]octa-2,6-diene, although a symmetry-allowed process, does not occur appreciably in 85 min. at 450°.

Article information

Article type
Paper

J. Chem. Soc. D, 1969, 1354-1355

Geometrical orbital overlap requirements in allowed thermal reactions: the trans,trans Cope rearrangement of 3,7-dideuteriobicyclo[3,3,0]octa-2,6-diene

J. E. Baldwin and M. S. Kaplan, J. Chem. Soc. D, 1969, 1354 DOI: 10.1039/C29690001354

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements