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13 C-Labelled precursors and spectral methods show that the terphenyl ring system of phlebiarubrone can be derived from phenylalanine and the methylene group from formate: the relative proportion of doubly-labelled and singly-labelled metabolite reveals the amount of endogenous phenylalanine available for the biosynthesis of phlebiarubrone through the dimerization of a C6–C3 unit.
A. K. Bose, K. S. Khanchandani, P. T. Funke and M. Anchel, J. Chem. Soc. D, 1969, 1347 DOI: 10.1039/C29690001347
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