The pKa values of a series of 6-substituted spiro[3,3]heptane-2-carboxylic acids have been measured in 50%(by wt.) aqueous ethanol and the results analysed in terms of the mechanism of transmission of nonconjugative substituent effects.
C. L. Liotta, W. F. Fisher and G. H. Greene, J. Chem. Soc. D, 1969, 1251 DOI: 10.1039/C29690001251
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