A primary isotope effect observed in the decomposition rate of t-butyl peroxide in [O-2H1]butan-2-ol indicates transfer of the oxygen-bonded hydrogen occurs in the induced decomposition of the peroxide by the alcohol-derived α-hydroxy-alkyl radical.
E. S. Huyser and A. A. Kahl, J. Chem. Soc. D, 1969, 1238 DOI: 10.1039/C29690001238
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