In the polymerisation of 1,3-dioxolan by Et3O+BF4– the formation of active centres (which are stable when formed) is slow, and it is accompanied by competitive hydride abstraction from monomer and decomposition of the catalyst.
F. R. Jones and P. H. Plesch, J. Chem. Soc. D, 1969, 1230 DOI: 10.1039/C29690001230
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