The mechanism of racemisation of 2,3-dihydro-3R-iodomethyl-6-methoxycarbonyl-1,4-thiazine: a novel bond-switching
Abstract
2,3-Dihydro-3R-iodomethyl-6-methoxycarbonyl 1,4-thiazine undergoes a thermally-induced racemisation during which the 2- and the exocyclic-methylene groups become equivalent.