Methyl 3-acetamido-3,6-dideoxy-2-O-methane-sulphonyl-α-L-glucopyranoside, on heating with sodium methoxide in methanol, gives the ring-contracted compound (2) and its (R)-diastereoisomer (3).
K. Čapek, J. Jarý and Z. Samek, J. Chem. Soc. D, 1969, 1162 DOI: 10.1039/C29690001162
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