Kinetic studies of the substitution reactions of [Pd(1,1,7,7-tetraethyldiethylenetriamine)XCN]+ with bromide ion in dimethylformamide indicate that, for X = S, an SNI or solvent-assisted ligand interchange process is operative whereas, for X = Se, a concurrent SN2 path involving chelate ring-opening is also involved—a unique example of mechanistic control by an outgoing group.
J. L. Burmeister and J. C. Lim, J. Chem. Soc. D, 1969, 1154 DOI: 10.1039/C29690001154
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