The spectroscopic and chemical properties of the bicyclo[5,3,1]undec-7-en-11-one derivative (I) are abnormal, and can be interpreted in terms of the geometry of the molecule as revealed by an X-ray crystallographic analysis, carried out on (II).
G. L. Buchanan, A. F. Cameron and G. Jamieson, J. Chem. Soc. D, 1969, 1145 DOI: 10.1039/C29690001145
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