ortho-1,4-Addition is the predominant reaction between m-methoxybenzyl Grignard reagent and methyl vinyl ketone but it is sharply reduced in the presence of copper(I) chloride.
S. Danishefsky and B. H. Migdalof, J. Chem. Soc. D, 1969, 1107 DOI: 10.1039/C29690001107
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