SCHEDULED MAINTENANCE
The “abnormal” Beckmann rearrangement of [4α-CD3]-4,4-dimethyl-5α-cholestan-3-one oxime gives predominantly the dideuterio-seco-nitrile via a seven-membered ring tosyloxy-imine.
G. P. Moss and S. A. Nicolaidis, J. Chem. Soc. D, 1969, 1077 DOI: 10.1039/C29690001077
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