Novel dialkylamides of TiIII which have alkylamido-bridged structures and exhibit fluxional behaviour and strong metal–metal interactions, together with the TiII derivatives obtained by disproportionation 2TiX(NR2)2→ TiX2+ Ti(NR2)4, afford valuable starting materials for the synthesis of bivalent and tervalent titanium complexes.
E. C. Alyea, D. C. Bradley, M. F. Lappert and A. R. Sanger, J. Chem. Soc. D, 1969, 1064 DOI: 10.1039/C29690001064
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