The stereochemical direction (retention or inversion) of nucleophilic displacements at phosphorus in acyclic t-butylphosphonium salts depends on the nature of the leaving group.
R. A. Lewis, K. Naumann, K. E. DeBruin and K. Mislow, J. Chem. Soc. D, 1969, 1010 DOI: 10.1039/C29690001010
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