Processes (arenesulphonate solvolysis and deamination via the arylalkyltriazene) involving a 2-adamantyl cation as intermediate lead to products free from 1-substituted adamantanes but containing tricyclo-[4,3,1,03,8]decane derivatives.
M. L. Sinnott, H. J. Storesund and M. C. Whiting, J. Chem. Soc. D, 1969, 1000 DOI: 10.1039/C29690001000
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