α-Chlorination of dialkyl and aryl alkyl sulphoxides by iodobenzene dichloride is highly stereospecific, and in benzyl methyl sulphoxide involves the proton diastereotopic to that which is preferentially exchanged by deuterium in NaOD–D2O.
M. Cinquini, S. Colonna and F. Montanari, J. Chem. Soc. D, 1969, 607 DOI: 10.1039/C29690000607
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