The commonly accepted mechanism for the substitution of a ligand at a solvated metal ion fails to explain solvent effects on the kinetics of reaction of nickel(II) ion with bipyridyl, for which a correlation with fluidity is noted.
H. P. Bennetto and E. F. Caldin, J. Chem. Soc. D, 1969, 599 DOI: 10.1039/C29690000599
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