The crystal structures of two diastereoisomeric β2-cobalt(III)–triethylenetetramine-S-proline complexes are presented and the relative stabilities of the two complexes are exemplified by bond angle distortions in the less stable isomer.
D. A. Buckingham, L. G. Marzilli, I. E. Maxwell, A. M. Sargeson and H. C. Freeman, J. Chem. Soc. D, 1969, 583 DOI: 10.1039/C29690000583
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