Hydrogen transfer is rate-limiting in homogeneous hydrogenation of cycloalkenes by [py2(dmf)-RhCl2(BH4)] in dimethylformamide (dmf) solution, as in heterogeneous hydrogenation.
I. Jardine and F. J. McQuillin, J. Chem. Soc. D, 1969, 502 DOI: 10.1039/C29690000502
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