Infrared evidence suggests that CO loss follows Cd line (2288 Å) photolysis of HMn(CO)5 in argon at 15°K and that the photolysis can be reversed by use of λ > 2850 Å.
A. J. Rest and J. J. Turner, J. Chem. Soc. D, 1969, 375 DOI: 10.1039/C29690000375
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