A comparison of several nucleophilic reagents for the determination of aliphatic aldehydes via polarography of their azomethine derivatives has been made. The reduction of Girard T derivatives was found to give the best defined waves under the experimental conditions used. The E1/2 values for the reduction of the azomethine grouping were found to fit the modified Taft relationship.
B. Fleet and P. N. Keliher, Analyst, 1969, 94, 659 DOI: 10.1039/AN9699400659
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
