The use of exciting X-rays with energies either just above or far above the X-ray absorption edge of the wanted element has been proposed for radio-isotope X-ray fluorescence analysis. The performance of these two methods is compared in terms of limits of detection, reduction of heterogeneity effects and compensation for matrix effects.
K. G. Carr-Brion, Analyst, 1969, 94, 177 DOI: 10.1039/AN9699400177
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