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The energy parameters associated with internal rotation in a series of butanes and propanes have been derived from spectroscopic and molecular acoustic measurements. These data include enthalpy differences and barrier heights and these are discussed in terms of non-bonded interactions.
E. Wyn-Jones and W. J. Orville-Thomas, Trans. Faraday Soc., 1968, 64, 2907 DOI: 10.1039/TF9686402907
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